{"id":86,"date":"2020-09-02T01:12:52","date_gmt":"2020-09-01T17:12:52","guid":{"rendered":"https:\/\/people.utm.my\/mfadhzir\/?p=86"},"modified":"2022-11-04T00:13:11","modified_gmt":"2022-11-03T16:13:11","slug":"phosphoric-acid-doped-composite-proton-exchange-membrane-for-hydrogen-production-in-medium-temperature-copper-chloride-electrolysis","status":"publish","type":"post","link":"https:\/\/people.utm.my\/mfadhzir\/2020\/09\/02\/phosphoric-acid-doped-composite-proton-exchange-membrane-for-hydrogen-production-in-medium-temperature-copper-chloride-electrolysis\/","title":{"rendered":"Hydrogen production in medium-temperature copper chloride electrolysis"},"content":{"rendered":"<div class=\"row\">\n<div class=\"col-xs-10\">\n<section id=\"articleTitleInfo\" class=\"list-group marginTop1 noMarginLeft paddingTop1\"><span id=\"publicationTitle\" class=\"list-group-item\"><a class=\"secondaryLink\" title=\"Go to the information page for this source\" href=\"https:\/\/www.scopus.com\/sourceid\/26991?origin=recordpage\"><span class=\"anchorText\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-34 size-large\" src=\"https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-768x1024.jpg\" alt=\"\" width=\"604\" height=\"805\" srcset=\"https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-768x1024.jpg 768w, https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-225x300.jpg 225w, https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-1152x1536.jpg 1152w, https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-1536x2048.jpg 1536w, https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-1200x1600.jpg 1200w, https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-1980x2640.jpg 1980w, https:\/\/people.utm.my\/mfadhzir\/wp-content\/uploads\/sites\/2351\/2020\/08\/IJHE-published-45-2020-22209-22222-page-001-scaled.jpg 1920w\" sizes=\"auto, (max-width: 604px) 100vw, 604px\" \/>International Journal of Hydrogen Energy<\/span><\/a><\/span><\/section>\n<section class=\"list-group marginTop1 noMarginLeft paddingTop1\"><span id=\"journalInfo\" class=\"list-group-item\">Volume 45, Issue 42, 28 August 2020, Pages 22209-22222<\/span><\/section>\n<\/div>\n<section id=\"viewPdfButtonSection\">\n<div class=\"col-xs-2\">\n<div id=\"viewPdfButtonDiv\" class=\"pull-right\"><\/div>\n<\/div>\n<\/section>\n<\/div>\n<div>\n<h2 class=\"h3\"><a href=\"https:\/\/www.scopus.com\/redirect\/linking.uri?targetURL=https%3a%2f%2fdoi.org%2f10.1016%2fj.ijhydene.2019.10.030&amp;locationID=1&amp;categoryID=4&amp;eid=2-s2.0-85075398332&amp;issn=03603199&amp;linkType=ViewAtPublisher&amp;year=2020&amp;origin=recordpage&amp;dig=781c6d253e40d84b8c145b87c901a85a&amp;recordRank=\">Phosphoric acid doped composite proton exchange membrane for hydrogen production in medium-temperature copper chloride electrolysis (Article)<\/a><\/h2>\n<section id=\"authorlist\">\n<ul class=\"list-inline\">\n<li><span class=\"anchorText\"><span class=\"ScopusTermHighlight\"><a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=26221132900&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_b\">Kamaroddin, M.F.A.<sup>a<\/sup><sup>,b<\/sup><\/a>, <\/span><\/span><span class=\"anchorText\"><a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=55755204300&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_d\">Sabli, N.<sup>a<\/sup><sup>,d<\/sup><\/a><\/span><a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=56979200800&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_b\"><span class=\"anchorText\">,Nia, P.M.<sup>b<\/sup><\/span><\/a>,\u00a0<a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=35753924700&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_c\"><span class=\"anchorText\">Abdullah, T.A.T.<sup>b<\/sup><sup>,c<\/sup><\/span><\/a>,<a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=57204712486&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_a\"><span class=\"anchorText\">Abdullah, L.C.<sup>a<\/sup><\/span><\/a>,<a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=24176682700&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_a\"><span class=\"anchorText\">Izhar, S.<sup>a<\/sup><\/span><\/a>, <a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=35109605300&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_c\"><span class=\"anchorText\">Ripin, A.<sup>b<\/sup><sup>,c<\/sup><\/span><\/a>, <a title=\"Show Author Details\" href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=57216511821&amp;amp;eid=2-s2.0-85075398332\" aria-labelledby=\"superscript_c\"><span class=\"anchorText\">Ahmad, A.<sup>b<\/sup><sup>,c<\/sup><\/span><\/a><\/li>\n<\/ul>\n<\/section>\n<section id=\"affiliationlist\">\n<ul class=\"list-unstyled\">\n<li id=\"superscript_a\"><sup>a<\/sup>Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Serdang, Selangor 43400, Malaysia<\/li>\n<li id=\"superscript_b\"><sup>b<\/sup>Centre of Hydrogen Energy, Institute of Future Energy, Universiti Teknologi Malaysia, Skudai, Johor 81310, Malaysia<\/li>\n<li id=\"superscript_c\"><sup>c<\/sup>School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, Skudai, Johor 81310, Malaysia<\/li>\n<li id=\"superscript_d\"><sup>d<\/sup>Institute of Advanced Technology (ITMA), Universiti Putra Malaysia, UPM Serdang, Selangor 43400, Malaysia<\/li>\n<\/ul>\n<h3 class=\"h4\">Abstract<span id=\"viewRefPH\" class=\"pull-right show\"><\/span><\/h3>\n<p>A copper chloride (CuCl) electrolyzer that constitutes of composite proton exchange membrane (PEM) that functions at medium-temperature (&gt;100 \u00b0C) is beneficial for rapid electrochemical kinetics and better in handling fuel pollutants. A synthesized polybenzimidazole (PBI) composite membrane from the addition of ZrO<sub>2<\/sub>\u00a0followed with phosphoric acid (PA) is suggested to overcome the main issues in CuCl electrolysis, including the copper diffusion and proton conductivity. PBI\/ZrP properties improved significantly with enhanced proton conductivity (3 fold of pristine PBI, 50% of Nafion 117), superior thermal stability (&gt;600 \u00b0C), good mechanical strength (85.17 MPa), reasonable Cu permeability (7.9 \u00d7 10<sup>\u22127<\/sup>) and high ionic exchange capacity (3.2 \u00d7 10<sup>\u22123<\/sup>\u00a0mol g<sup>\u22121<\/sup>). Hydrogen produced at 0.5 A cm<sup>\u22122<\/sup>\u00a0(115 \u00b0C) for PBI\/ZrP and Nafion 117 was 3.27 cm<sup>3<\/sup>\u00a0min<sup>\u22121<\/sup>\u00a0and 1.85 cm<sup>3<\/sup>\u00a0min<sup>\u22121<\/sup>, respectively. The CuCl electrolyzer efficiency was ranging from 91 to 97%, thus proven that the hybrid PBI\/ZrP membrane can be a promising and cheaper alternative to Nafion membrane. \u00a9 2019 Hydrogen Energy Publications LLC<\/p>\n<\/section>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>International Journal of Hydrogen Energy Volume 45, Issue 42, 28 August 2020, Pages 22209-22222 Phosphoric acid doped composite proton exchange membrane for hydrogen production in medium-temperature copper chloride electrolysis (Article) Kamaroddin, M.F.A.a,b, Sabli, N.a,d,Nia, P.M.b,\u00a0Abdullah, T.A.T.b,c,Abdullah, L.C.a,Izhar, S.a, Ripin, A.b,c, &hellip; <a href=\"https:\/\/people.utm.my\/mfadhzir\/2020\/09\/02\/phosphoric-acid-doped-composite-proton-exchange-membrane-for-hydrogen-production-in-medium-temperature-copper-chloride-electrolysis\/\">Continue reading <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":25178,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[58,21,20,10],"tags":[46,25,27,36,22],"class_list":["post-86","post","type-post","status-publish","format-standard","hentry","category-achievements-experiences","category-high-impact-paper","category-phd-journey","category-rd","tag-composite-membrane","tag-composite-pem","tag-copper-chloride-electrolysis","tag-hydrogen-production","tag-phosphoric-acid"],"_links":{"self":[{"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/posts\/86","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/users\/25178"}],"replies":[{"embeddable":true,"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/comments?post=86"}],"version-history":[{"count":5,"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/posts\/86\/revisions"}],"predecessor-version":[{"id":464,"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/posts\/86\/revisions\/464"}],"wp:attachment":[{"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/media?parent=86"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/categories?post=86"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/people.utm.my\/mfadhzir\/wp-json\/wp\/v2\/tags?post=86"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}